Beryllium

2008/9 Schools Wikipedia Selection. Related subjects: Chemical elements

4 lithium ← beryllium → boron - ↑ Be ↓ Mg Periodic table - Extended periodic table
General
Name, symbol, number	beryllium, Be, 4
Chemical series	alkaline earth metals
Group, period, block	2,  2, s
Appearance	white-gray metallic
Standard atomic weight	9.012182 (3) g·mol−1
Electron configuration	1s2 2s2
Electrons per shell	2, 2
Physical properties
Phase	solid
Density (near r.t.)	1.85 g·cm−3
Liquid density at m.p.	1.690 g·cm−3
Melting point	1560  K (1287 ° C, 2349 ° F)
Boiling point	2742 K (2469 ° C, 4476 ° F)
Heat of fusion	7.895 kJ·mol−1
Heat of vaporization	297 kJ·mol−1
Specific heat capacity	(25 °C) 16.443 J·mol−1·K−1
Vapor pressure P/Pa 1 10 100 1 k 10 k 100 k at T/K 1462 1608 1791 2023 2327 2742
Atomic properties
Crystal structure	hexagonal
Oxidation states	2, 1 ( amphoteric oxide)
Electronegativity	1.57 (Pauling scale)
Ionization energies ( more)	1st: 899.5 kJ·mol−1
	2nd: 1757.1 kJ·mol−1
	3rd: 14848.7 kJ·mol−1
Atomic radius	105 pm
Atomic radius (calc.)	112 pm
Covalent radius	90 pm
Miscellaneous
Magnetic ordering	diamagnetic
Thermal conductivity	(300 K) 200 W·m−1·K−1
Thermal expansion	(25 °C) 11.3 µm·m−1·K−1
Speed of sound (thin rod)	( r.t.) 12870  m·s−1
Young's modulus	287 GPa
Shear modulus	132 GPa
Bulk modulus	130 GPa
Poisson ratio	0.032
Mohs hardness	5.5
Vickers hardness	1670 MPa
Brinell hardness	600 MPa
CAS registry number	7440-41-7
Selected isotopes
Main article: Isotopes of beryllium iso NA half-life DM DE ( MeV) DP 7Be trace 53.12 d ε - 7Li γ 0.477 - 9Be 100% 9Be is stable with 5 neutrons 10Be trace 1.51×106 y β- 0.556 10B
References

Beryllium (pronounced /bəˈrɪliəm/) is a chemical element with the symbol Be and atomic number 4. A bivalent element, beryllium is a steel grey, strong, light-weight yet brittle, alkaline earth metal. It is primarily used as a hardening agent in alloys, most notably beryllium copper. Commercial use of beryllium metal presents technical challenges due to the toxicity (especially by inhalation) of beryllium-containing dusts.

Beryllium is relatively rare element in both the Earth and the universe, due to the fact that it is not formed in conventional stellar nucleosynthesis. The element is not known to be necessary or useful for either plant or animal life.

Properties

• It has one of the highest melting points of the light metals. The modulus of elasticity of beryllium is approximately a third greater than that of steel. The combination of this modulus plus beryllium's relatively low density gives it the fastest sound conduction speed of any solid at standard conditions (about 12.9 km/sec). It has excellent thermal conductivity and is nonmagnetic.
• It is highly permeable to X-rays, and neutrons are liberated when it is hit by alpha particles, as from radium or polonium (about 30 neutrons/million alpha particles).
• At standard temperature and pressures beryllium resists oxidation when exposed to air (although its ability to scratch glass is probably due to the formation of a thin layer of the oxide). It resists attack by concentrated nitric acid.

History

This element was discovered by Louis-Nicolas Vauquelin in 1798 as the oxide in beryl and in emeralds. Friedrich Wöhler and A. A. Bussy independently isolated the metal in 1828 by reacting potassium and beryllium chloride.

Etymology

The name beryllium comes from the Greek βερυλλος, beryllos, beryl, from Prakrit veruliya, from Pāli veuriya; akin or perhaps akin to Tamil language veiru or, viar, "to become pale," in reference to the pale semiprecious gemstone beryl. At one time beryllium was referred to as glucinium (from Greek, sweet), due to the sweet taste of its salts (with the accompanying chemical symbol "Gl").

Applications

Mechanical

• Due to its stiffness, light weight, and dimensional stability over a wide temperature range, Beryllium metal is used in the defense and aerospace industries as light-weight structural materials in high-speed aircraft, missiles, space vehicles, and communication satellites. For example, many high-quality liquid fueled rockets use nozzles of pure Be, an example being the Saturn V.
• Beryllium is used as an alloying agent in the production of beryllium copper, which contains up to 2.5% beryllium. Beryllium-copper alloys are used in a wide variety of applications because of their combination of high electrical and thermal conductivity, high strength and hardness, nonmagnetic properties, along with good corrosion and fatigue resistance. These applications include the making of spot-welding electrodes, springs, non-sparking tools and electrical contacts.
• In the telecommunications industry, tools made of beryllium are used to tune the highly magnetic klystrons used for high power microwave applications.
• Beryllium copper is used in electrical spring contacts.
• Beryllium is used in the making of gyroscopes, computer equipment, watch springs and instruments where light-weight, rigidity and dimensional stability are needed.
• The James Webb Space Telescope will have 18 hexagonal beryllium sections for its mirrors. Because JWST will face a temperature of −240 degrees Celsius (33 kelvins), the mirror is made of beryllium, a material capable of handling extreme cold better than glass. Beryllium contracts and deforms less than glass — and thus remains more uniform — in such temperatures. For the same reason, the optics of the Spitzer Space Telescope are entirely built of beryllium metal.
• Beryllium has been used in tweeter and mid-range audio loudspeaker construction as an alternative to titanium and aluminium, largely due to its lower density and greater rigidity.

Radiation

A square beryllium foil mounted in a steel case to be used as a window between a vacuum chamber and an X-ray microscope. Beryllium, due to its low Z number is highly transparent to X-rays.

• Thin sheets of beryllium foil are used as windows in X-ray detectors to filter out visible light and allow only X-rays to be detected.
• Sheets of beryllium ranging from 3 millimetres (0.12 in) thick down to 25 micrometres (0.00098 in) thick are used as the output window in x-ray tubes, allowing x-rays to leave the tube while keeping a vacuum on the inside of the tube.
• In the field of X-ray lithography beryllium is used for the reproduction of microscopic integrated circuits.
• Because of its low atomic number beryllium is almost transparent to energetic electrically charged particles. Therefore it is used to build the beam pipe around the collision region in collider particle physics experiments. Notably all four main detector experiments at the Large Hadron Collider accelerator ( ALICE, ATLAS, CMS, LHCb) use a beryllium beam-pipe.

Nuclear

• Beryllium is used in nuclear weapon designs as the outer layer of the pit of the primary stage, surrounding the fissile material. It is a good pusher for implosion, and the best possible neutron reflector, reducing the critical mass needed for a fission chain reaction and increasing the proportion of fuel that fissions, while itself adding little mass to the weapon. It is a poor tamper because of its low mass, but this is unimportant in fusion- boosted fission weapons. As a light element with few electrons, the fission explosion completely ionizes it quickly, making it transparent to X-rays and letting the energy from a primary fission explosion escape for radiation implosion of a secondary fusion stage.
• Beryllium is a good neutron moderator because it has a low neutron absorption cross section, and because light nuclei are more effective at slowing down neutrons than heavy nuclei. It has been used in some nuclear reactors; see Category:Beryllium moderated reactors.
• Beryllium is sometimes used in neutron sources, in which the beryllium is mixed with an alpha emitter such as ²¹⁰Po, ²²⁶Ra, ²³⁹Pu or ²⁴¹Am.
• Beryllium is used in the Joint European Torus fusion research facility and will be used in ITER, to condition the plasma facing components.

Compounds

• Beryllium is an effective p-type dopant in III-V compound semiconductors. It is widely used in materials such as GaAs, AlGaAs, InGaAs, and InAlAs grown by molecular beam epitaxy (MBE).
• Beryllium oxide is useful for many applications that require the combined properties of an electrical insulator an excellent heat conductor, with high strength and hardness, with a very high melting point. Beryllium oxide is frequently used as an insulator base plate in high-power transistors in RF transmitters for telecommunications. Beryllium oxide is also being studied for use in increasing the thermal conductivity of uranium dioxide nuclear fuel pellets.
• Beryllium compounds were once used in fluorescent lighting tubes, but this use was discontinued because of berylliosis in the workers manufacturing the tubes (see below).

Occurrence on Earth

Beryllium is an essential constituent of about 100 out of about 4000 known minerals, the most important of which are bertrandite (Be₄Si₂O₇(OH)₂), beryl (Al₂Be₃Si₆O₁₈), chrysoberyl (Al₂BeO₄), and phenakite (Be₂SiO₄). Precious forms of beryl are aquamarine, bixbite and emerald.

The most important commercial sources of beryllium and its compounds are beryl and bertrandite. Beryllium metal did not become readily available until 1957. Currently, most production of this metal is accomplished by reducing beryllium fluoride with magnesium metal. The price on the US market for vacuum-cast beryllium ingots was 338 US$ per pound ($745/kg) in 2001.

BeF₂ + Mg → MgF₂ + Be

Isotopes

Of beryllium's isotopes, only ⁹Be is stable. Cosmogenic ¹⁰Be is produced in the atmosphere by cosmic ray spallation of oxygen and nitrogen. Because beryllium tends to exist in solutions below about pH 5.5 (and rainwater above many indutrialized areas can have a pH less than 5), it will dissolve and be transported to the Earth's surface via rainwater. As the precipitation quickly becomes more alkaline, beryllium drops out of solution. Cosmogenic ¹⁰Be thereby accumulates at the soil surface, where its relatively long half-life (1.51 million years) permits a long residence time before decaying to ¹⁰B. ¹⁰Be and its daughter products have been used to examine soil erosion, soil formation from regolith, the development of lateritic soils, as well as variations in solar activity and the age of ice cores. It is also formed in nuclear explosions by a reaction of fast neutrons with ¹³C in the carbon dioxide in air, and is one of the historical indicators of past activity at nuclear test sites.

Plot showing variations in solar activity, including variation in ¹⁰Be concentration.

The fact that ⁷Be and ⁸Be are unstable has profound cosmological consequences as it means that elements heavier than beryllium could not be produced by nuclear fusion in the Big Bang. However, Fred Hoyle showed that the energy levels of ⁸Be and ¹²C favour carbon production by the triple-alpha process in helium burning stars, thus making life possible. (See also Big Bang nucleosynthesis).

⁷Be decays by electron capture, therefore its decay rate is dependent upon its electron configuration - a novel occurrence in nuclear decay.

The shortest-lived known isotope of beryllium is ¹³Be which decays through neutron emission. It has a half-life of 2.7 × 10^-21 second. ⁶Be is also very short-lived with a half-life of 5.0 × 10^-21 second.

The exotics ¹¹Be and ¹⁴Be are known to exhibit a nuclear halo.

Precautions

Beryllium ore

According to the International Agency for Research on Cancer (IARC), beryllium and beryllium compounds are Category 1 carcinogens; they are carcinogenic to both animals and humans. Chronic berylliosis is a pulmonary and systemic granulomatous disease caused by exposure to beryllium. Acute beryllium disease in the form of chemical pneumonitis was first reported in Europe in 1933 and in the United States in 1943. Cases of chronic berylliosis were first described in 1946 among workers in plants manufacturing fluorescent lamps in Massachusetts. Chronic berylliosis resembles sarcoidosis in many respects, and the differential diagnosis is often difficult. It occasionally killed early workers in nuclear weapons design, such as Herbert Anderson .

Although the use of beryllium compounds in fluorescent lighting tubes was discontinued in 1949, potential for exposure to beryllium exists in the nuclear and aerospace industries and in the refining of beryllium metal and melting of beryllium-containing alloys, the manufacturing of electronic devices, and the handling of other beryllium-containing material.

Early researchers tasted beryllium and its various compounds for sweetness in order to verify its presence. Modern diagnostic equipment no longer necessitates this highly risky procedure and no attempt should be made to ingest this highly toxic substance. Beryllium and its compounds should be handled with great care and special precautions must be taken when carrying out any activity which could result in the release of beryllium dust (lung cancer is a possible result of prolonged exposure to beryllium laden dust).

This substance can be handled safely if certain procedures are followed. No attempt should be made to work with beryllium before familiarization with correct handling procedures.

A successful test for beryllium on different surface areas has been recently developed. The procedure uses fluorescence when beryllium is bound to sulfonated hydroxybenzoquinoline to detect up to 10 times lower than the recommended limit for beryllium concentration in the work place. Fluorescence increases with increasing beryllium concentration. The new procedure has been successfully tested on a variety of surfaces.

Inhalation

Beryllium can be harmful if inhaled and the effects depend on period of exposure. If beryllium concentrations in air are high enough (greater than 100 µg/m³), an acute condition can result, called acute beryllium disease, which resembles pneumonia. Occupational and community air standards are effective in preventing most acute lung damage. Long term exposure to beryllium can increase the risk of developing lung cancer. The more common and serious health hazard from beryllium today is chronic beryllium disease (CBD), discussed below. It continues to occur in industries as diverse as metal recycling, dental laboratories, alloy manufacturing, nuclear weapons production, defense industries, and metal machine shops that work with alloys containing small amounts of beryllium.

Chronic beryllium disease (CBD)

Some people (1-15%) become sensitive to beryllium. These individuals may develop an inflammatory reaction that principally targets the respiratory system and skin. This condition is called chronic beryllium disease (CBD), and can occur within a few months or many years after exposure to higher than normal levels of beryllium (greater than 0.02 µg/m³). This disease causes fatigue, weakness, night sweats and can cause difficulty in breathing and a persistent dry cough. It can result in anorexia, weight loss, and may also lead to right-side heart enlargement and heart disease in advanced cases. Some people who are sensitized to beryllium may not have any symptoms. The disease is treatable, but not curable with traditional drugs and medicine. CBD occurs when the body's immune system recognizes beryllium particles as foreign material and mounts an immune system attack against the particles. Because these particles are typically inhaled into the lungs, the lungs become the major site where the immune system responds, they become inflamed and fill with large numbers of white blood cells that accumulate wherever beryllium particles are found. These cells form balls around the beryllium particles called “ granulomas.” When enough of these develop, they interfere with the normal function of the organ. Over time, the lungs become stiff and lose their ability to help transfer oxygen from the air into the bloodstream. Patients with CBD develop difficulty inhaling and exhaling sufficient amounts of air, and the amount of oxygen in their bloodstreams falls. Treatment of such patients includes use of oxygen and medicines that try to suppress the immune system’s over-reaction to beryllium. A class of immunosuppressive medicines called glucocorticoids (example: prednisone) is most commonly used as treatment. The general population is unlikely to develop acute or chronic beryllium disease because ambient air levels of beryllium are normally very low (0.00003-0.0002 µg/m³).

Ingestion

Swallowing beryllium has not been reported to cause effects in humans because very little beryllium is absorbed from the stomach and intestines. Ulcers have been seen in dogs ingesting beryllium in their diet.

Dermatological effects

Beryllium can cause contact dermatitis. Beryllium contact with skin that has been scraped or cut may cause rashes, ulcers, or bumps under the skin called granulomas.

Effects on children

There are no studies on the health effects of children exposed to beryllium, although individual cases of CBD have been reported in children of beryllium workers from the 1940s. It is likely that the health effects seen in children exposed to beryllium will be similar to the effects seen in adults. It is unknown whether children differ from adults in their susceptibility to beryllium. It is unclear whether beryllium is teratogenic.

Detection in the body

Beryllium can be measured in the urine and blood. The amount of beryllium in blood or urine may not indicate time or quantity of exposure. Beryllium levels can also be measured in lung and skin samples. While such measurements may help establish that exposure has occurred, other tests are used to determine if that exposure has resulted in health effects. A blood test, the blood beryllium lymphocyte proliferation test (BeLPT), identifies beryllium sensitization and has predictive value for CBD. The BeLPT has become the standard test for detecting beryllium sensitization and CBD in individuals who are suspected of having CBD and to help distinguish it from similar conditions such as sarcoidosis. It is also the main test used in industry health programs to monitor whether disease is occurring among current and former workers who have been exposed to beryllium on the job. The test can detect disease that is at an early stage, or can detect disease at more advanced stages of illness as well. The BeLPT can also be performed using cells obtained from a person's lung by a procedure called "bronchoscopy."

Industrial release and occupational exposure limits

Typical levels of beryllium that industries may release into the air are of the order of 0.01 µg/m³, averaged over a 30-day period, or 2 µg/m³ of workroom air for an 8-hour work shift. Compliance with the current U.S. Occupational Safety and Health Administration (OSHA) permissible exposure limit for beryllium of 2 µg/m³ has been determined to be inadequate to protect workers from developing beryllium sensitization and CBD. The American Conference of Governmental Industrial Hygienists (ACGIH), which is an independent organization of experts in the field of occupational health, has proposed a threshold limit value (TLV) of 0.05 µg/m³ in a 2006 Notice of Intended Change (NIC). This TLV is 40 times lower than the current OHSA permissible exposure limit, reflecting the ACGIH analysis of best available peer-reviewed research data concerning how little airborne beryllium is required to cause sensitization and CBD. Because it can be difficult to control industrial exposures to beryllium, it is advisable to use any methods possible to reduce airborne and surface contamination by beryllium, to minimize the use of beryllium and beryllium-containing alloys whenever possible, and to educate people about the potential hazards if they are likely to encounter beryllium dust or fumes.