Neodymium

2008/9 Schools Wikipedia Selection. Related subjects: Chemical elements

60 praseodymium ← neodymium → promethium - ↑ Nd ↓ U Periodic Table - Extended Periodic Table
General
Name, Symbol, Number	neodymium, Nd, 60
Chemical series	lanthanides
Group, Period, Block	n/a, 6, f
Appearance	silvery white, yellowish tinge
Standard atomic weight	144.242 (3)  g·mol−1
Electron configuration	[Xe] 4f4 6s2
Electrons per shell	2, 8, 18, 22, 8, 2
Physical properties
Phase	solid
Density (near r.t.)	7.01  g·cm−3
Liquid density at m.p.	6.89  g·cm−3
Melting point	1297  K (1024 ° C, 1875 ° F)
Boiling point	3347  K (3074 ° C, 5565 ° F)
Heat of fusion	7.14   kJ·mol−1
Heat of vaporization	289   kJ·mol−1
Specific heat capacity	(25 °C) 27.45  J·mol−1·K−1
Vapor pressure P(Pa) 1 10 100 1 k 10 k 100 k at T(K) 1595 1774 1998 (2296) (2715) (3336)
Atomic properties
Crystal structure	hexagonal
Oxidation states	3 (mildly basic oxide)
Electronegativity	1.14 (Pauling scale)
Ionization energies ( more)	1st:  533.1   kJ·mol−1
	2nd:  1040  kJ·mol−1
	3rd:  2130  kJ·mol−1
Atomic radius	185   pm
Atomic radius (calc.)	206  pm
Miscellaneous
Magnetic ordering	ferromagnetic
Electrical resistivity	( r.t.) (α, poly) 643 nΩ·m
Thermal conductivity	(300 K) 16.5  W·m−1·K−1
Thermal expansion	( r.t.) (α, poly) 9.6 µm/(m·K)
Speed of sound (thin rod)	(20 °C) 2330 m/s
Young's modulus	(α form) 41.4  GPa
Shear modulus	(α form) 16.3  GPa
Bulk modulus	(α form) 31.8  GPa
Poisson ratio	(α form) 0.281
Vickers hardness	343  MPa
Brinell hardness	265  MPa
CAS registry number	7440-00-8
Selected isotopes
Main article: Isotopes of neodymium iso NA half-life DM DE ( MeV) DP 142Nd 27.2% 142Nd is stable with 82 neutrons 143Nd 12.2% 143Nd is stable with 83 neutrons 144Nd 23.8% 2.29×1015y α 1.905 140Ce 145Nd 8.3% 145Nd is stable with 85 neutrons 146Nd 17.2% 146Nd is stable with 86 neutrons 148Nd 5.7% 148Nd is stable with 88 neutrons 150Nd 5.6% 6.7×1018y β-β- 3.367 150Sm
References

Neodymium (pronounced /ˌniːoʊˈdɪmiəm/) is a chemical element with the symbol Nd and atomic number 60.

Notable characteristics

Neodymium, a rare earth metal, is present in Mischmetal to the extent of about 18%. The metal has a bright, silvery metallic luster, however, as one of the more reactive rare earth metals, it quickly tarnishes in air. The tarnishing forms an oxide layer that falls off, which exposes the metal to further oxidation. Although it belongs to "rare earth metals," neodymium is not rare at all. It constitutes 38 ppm of Earth’s crust.

Applications

• Neodymium magnets are the strongest permanent magnets known - Nd₂Fe₁₄B. These magnets are cheaper, lighter, and stronger than samarium-cobalt magnets. Neodymium magnets appear in high-quality products such as microphones, professional loudspeakers, in-ear headphones, Dokodemo Magnets, guitar and bass guitar pick-ups and computer hard disks where low mass, small volume, or strong magnetic fields are required.
• Neodymium is a component of didymium used for coloring glass to make welder's and glass-blower's goggles. The sharp absorption bands obliterate the strong sodium emission at 589 nm.
• Neodymium lamps are incandescent lamps containing neodymium in the glass to filter out yellow light, resulting in a whiter light more like sunlight
• Neodymium colors glass in delicate shades ranging from pure violet through wine-red and warm grey. Light transmitted through such glass shows unusually sharp absorption bands; the glass is used in astronomical work to produce sharp bands by which spectral lines may be calibrated. Neodymium is also used to remove the green colour caused by iron contaminants from glass.
• Neodymium salts are used as a colourant for enamels.
• Probably because of similarities to Ca²⁺, Nd³⁺ has been reported to promote plant growth. Rare earth element compounds are frequently used in China as fertilizer.
• Samarium-neodymium dating is useful for determining the age relationships of rocks and meteorites.
• Size and strength of volcanic eruption can be predicted by scanning for neodymium isotopes. Small and large volcanic eruptions produce lava with different neodymium isotope composition. From the composition of isotopes, scientists predict how big the coming eruption will be, and use this information to warn residents of the intensity of the eruption.
• Certain transparent materials with a small concentration of neodymium ions can be used in lasers as gain media for infrared wavelengths (1054-1064 nm), e.g. Nd:YAG (yttrium aluminium garnet), Nd:YLF (yttrium lithium fluoride), Nd:YVO₄ (yttrium orthovanadate), and Nd:glass. The current laser at the UK Atomic Weapons Establishment (AWE), the HELEN 1-TW neodymium-glass laser, can access the midpoints of pressure and temperature regions and is used to acquire data for modeling on how density, temperature and pressure interact inside warheads. HELEN can create plasmas of around 10⁶ K, from which opacity and transmission of radiation are measured.

Neodymium glass

Neodymium glass (Nd:Glass) is produced by the inclusion of neodymium oxide (Nd₂O₃) in the glass melt. In daylight or incandescent light neodymium glass appears lavender, but it appears pale blue under fluorescent lighting.

Neodymium glass solid-state lasers are used in extremely high power ( terawatt scale), high energy ( megajoules) multiple beam systems for inertial confinement fusion. Nd:Glass lasers are usually frequency tripled to the third harmonic at 351 nm in laser fusion devices.

Neodymium doped glass slabs used in extremely powerful lasers for inertial confinement fusion.

Neodymium glass is becoming widely used in incandescent light bulbs, to provide a more "natural" light.

Neodymium glass has been patented for use in automobile rear-view mirrors, to reduce the glare at night.

The first commercial use of purified neodymium was in glass coloration, starting with experiments by Leo Moser in November 1927. The resulting "Alexandrite" glass remains a signature color of the Moser glassworks to this day. Neodymium glass was widely emulated in the early 1930's by American glasshouses, most notably Heisey, Fostoria ("wisteria"), Cambridge ("heatherbloom"), and Steuben ("wisteria"), and elsewhere (e.g. Lalique, in France, or Murano). Tiffin's "twilight" remained in production from about 1950 to about 1980. Current sources include glassmakers in the Czech Republic, the USA, and China; Caithness Glass in Scotland has also used the colorant extensively. The sharp absorption bands of neodymium cause the glass color to change under different lighting conditions, being reddish-purple under daylight or yellow incandescent light, but blue under white fluorescent lighting, or greenish under trichromatic lighting. This color-change phenomenon is highly prized by collectors. Neodymium in combination with praseodymium gave Moser's "Heliolite" glass. In combination with gold or selenium, beautiful red colors result, such as Moser's "Royalite" or Tiffin's "Wistaria" or some of the colors achieved by Fenton. Since neodymium coloration depends upon "forbidden" f-f transitions deep within the atom, there is relatively little influence on the color from the chemical environment, so the color is impervious to the thermal history of the glass. However, for the best color, iron-containing impurities need to be minimized in the silica used to make the glass. The same "forbiddenness" of the f-f transitions makes rare earth colorants less intense than those provided by most d-transition elements, so more has to be used in a glass to achieve the desired colour intensity. The original Moser recipe used about 5% of neodymium oxide in the glass melt, a sufficient quantity such that Moser referred to these as being "Rare Earth Doped" glasses. Being a strong base, that level of neodymium would have affected the melting properties of the glass, and the lime content of the glass might have had to be adjusted accordingly.

History

Neodymium was discovered by Baron Carl Auer von Welsbach, an Austrian chemist, in Vienna in 1885. He separated neodymium, as well as the element praseodymium, from a material known as didymium by means of fractional crystallization of the double ammonium nitrate tetrahydrates from nitric acid, while following the separation by spectroscopic analysis; however, it was not isolated in relatively pure form until 1925. The name neodymium is derived from the Greek words neos, new, and didymos, twin. Neodymium is frequently misspelled as neodynium.

Double nitrate crystallization was the means of commercial neodymium purification until the 1950's. The Lindsay Chemical Division of American Potash and Chemical Corporation, at one time the largest producer of rare earths in the world, offered neodymium oxide purified in this manner in grades of 65%, 85% and 95% purity, at prices ranging from approximately 2 to 20 dollars per pound (in 1960 dollars). Lindsay was the first to commercialize large-scale ion-exchange purification of neodymium, using the technology developed by Frank Spedding at Iowa State University/Ames Laboratory; one pound of their 99% oxide was priced at $35 in 1960; their 99.9% grade only cost 5 dollars more. Starting in the 1950's, high purity (e.g. 99+%) neodymium was primarily obtained through an ion exchange process from monazite sand ((Ce,La,Th,Nd,Y)PO₄), a material rich in rare earth elements. The metal itself is obtained through electrolysis of its halide salts. Currently, most neodymium is extracted from bastnaesite, (Ce,La,Nd,Pr)CO₃F, and purified by solvent extraction. Ion-exchange purification is reserved for preparing the highest purities (typically >4N). (When Molycorp first introduced their 98% grade of neodymium oxide in 1965, made by solvent extraction from Mountain Pass California bastnaesite, it was priced at 5 dollars per pound, for small quantities. Lindsay soon discontinued operations.) The evolving technology, and improved purity of commercially available neodymium oxide was reflected in the appearance of neodymium glass made therefrom, that resides in collections today. Early Moser pieces, and other neodymium glass made in the 1930's, have a more reddish or orange tinge than modern versions, which are more cleanly purple, due to the difficulties in removing the last traces of praseodymium, when the fractional crystallization technology had to be relied on.

Occurrence

Neodymium is never found in nature as the free element; rather, it occurs in ores such as monazite sand ((Ce,La,Th,Nd,Y)PO₄) and bastnäsite ((Ce,La,Th,Nd,Y)(CO₃)F) that contain small amounts of all the rare earth metals. Neodymium can also be found in Misch metal; it is difficult to separate it from other rare earth elements.

Compounds

Neodymium compounds include

• Halides: NdF₃, NdCl₃, NdBr₃, NdI₃
• Oxides: Nd₂O₃
• Sulfides: NdS, Nd₂S₃
• Nitrides: NdN

Isotopes

Naturally occurring Neodymium is composed of 5 stable isotopes, ¹⁴²Nd, ¹⁴³Nd, ¹⁴⁵Nd, ¹⁴⁶Nd and ¹⁴⁸Nd, with ¹⁴²Nd being the most abundant (27.2% natural abundance), and 2 radioisotopes, ¹⁴⁴Nd and ¹⁵⁰Nd. In all, 31 radioisotopes of Neodymium have been characterized up to now, with the most stable being naturally occurring isotopes ¹⁴⁴Nd ( alpha decay, a half-life (T_½) of 2.29×10¹⁵ years) and ¹⁵⁰Nd ( double beta decay, T_½ of 7×10¹⁸ years). All of the remaining radioactive isotopes have half-lives that are less than 11 days, and the majority of these have half-lives that are less than 70 seconds. This element also has 13 known meta states with the most stable being ^139mNd (T_½ 5.5 hours), ^135mNd (T_½ 5.5 minutes) and ^133m1Nd (T_½ ~70 seconds).

The primary decay modes before the most abundant stable isotope, ¹⁴²Nd, are electron capture and positron decay, and the primary mode after is beta minus decay. The primary decay products before ¹⁴²Nd are element Pr (praseodymium) isotopes and the primary products after are element Pm (promethium) isotopes.

Precautions

Neodymium metal dust is a combustion and explosion hazard.

Neodymium compounds, like all rare earth metals, are of low to moderate toxicity; however its toxicity has not been thoroughly investigated. Neodymium dust and salts are very irritating to the eyes and mucous membranes, and moderately irritating to skin. Breathing the dust can cause lung embolisms, and accumulated exposure damages the liver. Neodymium also acts as an anticoagulant, especially when given intravenously.

Neodymium magnets have been tested for medical uses such as magnetic braces and bone repair, but biocompatibility issues have prevented widespread application.