Thulium

2008/9 Schools Wikipedia Selection. Related subjects: Chemical elements

69 erbium ← thulium → ytterbium - ↑ Tm ↓ Md Periodic Table - Extended Periodic Table
General
Name, Symbol, Number	thulium, Tm, 69
Chemical series	lanthanides
Group, Period, Block	n/a, 6, f
Appearance	silvery gray
Standard atomic weight	168.93421 (2)  g·mol−1
Electron configuration	[Xe] 4f13 6s2
Electrons per shell	2, 8, 18, 31, 8, 2
Physical properties
Phase	solid
Density (near r.t.)	9.32  g·cm−3
Liquid density at m.p.	8.56  g·cm−3
Melting point	1818  K (1545 ° C, 2813 ° F)
Boiling point	2223  K (1950 ° C, 3542 ° F)
Heat of fusion	16.84   kJ·mol−1
Heat of vaporization	247   kJ·mol−1
Specific heat capacity	(25 °C) 27.03  J·mol−1·K−1
Vapor pressure P(Pa) 1 10 100 1 k 10 k 100 k at T(K) 1117 1235 1381 1570 (1821) (2217)
Atomic properties
Crystal structure	hexagonal
Oxidation states	3 ( basic oxide)
Electronegativity	1.25 (Pauling scale)
Ionization energies ( more)	1st:  596.7   kJ·mol−1
	2nd:  1160  kJ·mol−1
	3rd:  2285  kJ·mol−1
Atomic radius	175   pm
Atomic radius (calc.)	222  pm
Miscellaneous
Magnetic ordering	no data
Electrical resistivity	( r.t.) (poly) 676 nΩ·m
Thermal conductivity	(300 K) 16.9  W·m−1·K−1
Thermal expansion	( r.t.) (poly) 13.3 µm/(m·K)
Young's modulus	74.0  GPa
Shear modulus	30.5  GPa
Bulk modulus	44.5  GPa
Poisson ratio	0.213
Vickers hardness	520  MPa
Brinell hardness	471  MPa
CAS registry number	7440-30-4
Selected isotopes
Main article: Isotopes of thulium iso NA half-life DM DE ( MeV) DP 167Tm syn 9.25 d ε 0.748 167Er 168Tm syn 93.1 d ε 1.679 168Er 169Tm 100% 169Tm is stable with 100 neutrons 170Tm syn 128.6 d β- 0.968 170Yb 171Tm syn 1.92 y β- 0.096 171Yb
References

Thulium (pronounced /ˈθjuːliəm/) is a chemical element that has the symbol Tm and atomic number 69. A lanthanide element, thulium is the least abundant of the rare earths. It is an easily workable metal with a bright silvery-gray luster and can be cut by a knife. It has some corrosion resistance in dry air and good ductility. Naturally occurring thulium is made entirely of the stable isotope Tm-169.

Applications

• Thulium has been used to create laser light but high production costs have prevented other commercial uses from being developed.
• High temperature superconductors use thulium as a better cathode than yttrium.
• When stable, thulium (Tm-169) is bombarded in a nuclear reactor it can later serve as a radiation source in portable X-ray devices.
• The unstable isotope Tm-171 could possibly be used as an energy source.
• Tm-169 has potential use in ceramic magnetic materials called ferrites, which are used in microwave equipment.

History

Thulium was discovered by Swedish chemist Per Teodor Cleve in 1879 by looking for impurities in the oxides of other rare earth elements (this was the same method Carl Gustaf Mosander earlier used to discover some other rare earth elements). Cleve started by removing all of the known contaminants of erbia (Er₂O₃) and upon additional processing, obtained two new substances; one brown and one green. The brown substance turned out to be the oxide of the element holmium and was named holmia by Cleve and the green substance was the oxide of an unknown element. Cleve named the oxide thulia and its element thulium after Thule, Scandinavia.

Thulium was so rare that none of the early workers had enough of it to purify sufficiently to actually see the green colour; they had to be content with observing the strengthening of the two characteristic absorption bands, as erbium was progressively removed. The first researcher to obtain thulium nearly pure was the British expatriate working on a large scale at New Hampshire College in Durham NH: Charles James. In 1911, he reported his results, having used his discovered method of bromate fractional crystallization to do the purification. He famously needed 15,000 "operations" to establish that the material was homogeneous.

High purity thulium oxide was first offered commercially in the late 1950's, as a result of the adoption of ion-exchange separation technology. Lindsay Chemical Division of American Potash & Chemical Corporation offered it in grades of 99% and 99.9% purity, priced at US $850 or $900, respectively, per pound as of January 1959. This was the same price being asked for comparable grades of europium or terbium oxide; only lutetium oxide cost more (among the rare earths). The minimum order was one gram (at $4.50 or $5.00, depending on purity).

Occurrence

The element is never found in nature in pure form, but it is found in small quantities in minerals with other rare earths. It is principally extracted from monazite (~0.007% thulium) ores found in river sands through ion-exchange. Newer ion-exchange and solvent extraction techniques have led to easier separation of the rare earths, which has yielded much lower costs for thulium production. The principal source today are the ion adsorption clays of southern China. In the versions of these, where about two-thirds of the total rare earth content is yttrium, thulium is about 0.5% (or about tied with lutetium for rarity). The metal can be isolated through reduction of its oxide with lanthanum metal or by calcium reduction in a closed container. None of thulium's natural compounds are commercially important.

Thulium is a rare element used to power portable X-ray machines.

Isotopes

Naturally occurring thulium is composed of 1 stable isotope, Tm-169 (100% natural abundance). 31 radioisotopes have been characterized, with the most stable being Tm-171 with a half-life of 1.92 years, Tm-170 with a half-life of 128.6 days, Tm-168 with a half-life of 93.1 days, and Tm-167 with a half-life of 9.25 days. All of the remaining radioactive isotopes have half-lifes that are less than 64 hours, and the majority of these have half lifes that are less than 2 minutes. This element also has 14 meta states, with the most stable being Tm-164m (t_½ 5.1 minutes), Tm-160m (t_½ 74.5 seconds) and Tm-155m (t_½ 45 seconds).

The isotopes of thulium range in atomic weight from 145.966 u (Tm-146) to 176.949 u (Tm-177). The primary decay mode before the most abundant stable isotope, Tm-169, is electron capture, and the primary mode after is beta emission. The primary decay products before Tm-169 are element 68 (erbium) isotopes, and the primary products after are element 70 (ytterbium) isotopes.

Precautions

Thulium has a low-to-moderate degree of acute toxicity and should be handled with care. Metallic thulium in dust form presents a fire and explosion hazard.

Fiction

Thulium is used as interstellar money in the book Illegal Aliens (authors Nick Polotta and Phil Foglio), due to its rarity and lack of other uses.